Nicl4 is paramagnetic while nico4
Webb10 maj 2024 · The molecule [ PdCl 4] 2 − is diamagnetic, which indicates a square planar geometry as all eight d-electrons are paired in the lower-energy orbitals. However, [ NiCl 4] 2 − is also d 8 but has two unpaired electrons, indicating a tetrahedral geometry. Why is [ PdCl 4] 2 − square planar if Cl − is not a strong-field ligand? Solution Webb5 nov. 2024 · In [NiCl4]2-, due to the presence of Cl- a weak field ligand no pairing occurs whereas in [Ni (CN)4]2-, CN- is a strong field ligand and pairing takes …
Nicl4 is paramagnetic while nico4
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WebbClick here👆to get an answer to your question ️ Among Ni(CO)4 , [Ni(CN)4]^2 and NiCl4^2 - Solve Study Textbooks Guides. Join / Login >> Class 12 >> Chemistry >> Coordination Compounds >> Valency Bond Theory ... [N i C l 4 ] 2 − is paramagnetic while [N i ... WebbSolution: [N i(N H 3)4]2+: N i2+ undergoes sp3 -hybridisation, the resulting ion is paramagnetic due to the presence of two unpaired electrons. N i(CO)4 : Two 4s -electrons in Ni pair up with 3d -electrons followed by sp3 -hybridisation. The resulting complex has no unpaired electron and is diamagnetic. [N i(CN)4]2− : CN' being a strong ...
Webb6 juni 2024 · Under this condition, the electronic arrangement of Ni (II) ion is evidently shown that the 3d-orbitals of Ni (II) ion have '2' unpaired electrons and hence[ NiCl4 … Webb26 dec. 2024 · Correct option (a) Ni(CO) 4 - tetrahedral, paramagnetic. Explanation : In Ni(CO) 4 complex, Ni(CO) 4 will have 3d 10 configuration. Hence [Ni(CO) 4] will have …
WebbIn case of [NiCl4] 2−, Cl − ion is a weak field ligand. Therefore, it does not lead to the pairing of unpaired 3d electrons. Therefore, it undergoes sp3 hybridization. Since there … WebbIn [NiCl 4] 2-,Ni is in +2 oxidation state with the configuration 3d8 4so.Cl-ion being weak ligand,it cannot pair up the electrons in 3dorbitals.Hence,it is paramagnetic. In [Ni (CO) 4],Ni is in zero oxidation with the configuration 3d8 4s 2.In the presence of CO ligand,the 4s electrons shift to 3d to pair up 3d electrons.Thus,there is no unpaired electron present.
WebbClick here👆to get an answer to your question ️ Among Ni(CO)4 , [Ni(CN)4]^2 and NiCl4^2 - Solve Study Textbooks Guides. Join / Login >> Class 12 >> Chemistry >> …
WebbSolution 1 In [NiCl 4] 2−, Ni is in the +2 state. Cl − is a ligand which is a weak field ligand which does not cause pairing of unpaired 3d electrons. Hence, it is paramagnetic. In … fms proformaWebb296 Views Answer Explain on the basis of valence bond theory that [Ni (CN)4]2– ion with square planar is diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic. 2301 Views Answer List various types of isomerism possible for coordination compounds, giving an example of each. 229 Views Answer Advertisement … fms produceWebb24 okt. 2024 · Correct option (b) Ni(CO) 4, [Ni(CN) 4] 2- are diamagnetic but NiCl 4 2- is paramagnetic. Explanation: Ni (28) Ni 2+ both have two unpaired electrons. CO and … fms progressionWebb[NiCl 4] 2− shows dsp 2 hybridisation hence it is paramagnetic. D [Ni(CN) 4] 2−, shows sp 3 hybridisation hence it is diamagnetic. Medium Solution Verified by Toppr Correct option is B) [Ni(CN) 4] 2−, have 0 unpaired electrons are present and [NiCl 4] 2− having two unpaired electrons are present. Solve any question of Coordination Compounds with:- greenside carpet cleaning phone numberWebb#inorganicchemistry,#chemistryclass12,#coordinationcompound,#chemistrymcq,#coordinategeometry,1 quick revision on Aluminium and potash alum#p-block element ... fms productionWebbThough both [NiCl 4] 2− and [Ni (CO) 4] are tetrahedral, their magnetic characters are different. This is due to a difference in the nature of ligands. Cl − is a weak field ligand … green sideboard cards in legacyWebb25 dec. 2024 · But CO is a strong field ligand. Therefore, it causes the pairing of unpaired 3d electrons. Also, it causes the 4s electrons to shift to the 3d orbital, thereby giving rise to sp3hybridization. Since no unpaired electrons are present in this case, [Ni(CO)4] is diamagnetic. Please log inor registerto add a comment. ← Prev QuestionNext Question → greenside chemist opening times